2024-03-28T15:44:05Z
https://u-ryukyu.repo.nii.ac.jp/oai
oai:u-ryukyu.repo.nii.ac.jp:02007012
2022-10-31T03:13:15Z
1642837622505:1642837994858:1642838003490
1642838403551:1642838406414
The Ion-Solvent Interactions and Ionic Associations in Solvent Mixtures. 1. The Conductances of Potassium Halides and the Behaviovrs of Ions in n-Propanol-Water Mixtures at 25℃.
Uehara, Yosei
Moriyama, Tsugumasa
上原, 与盛
盛山, 紹政
open access
The quivalent conductances of KCl, KBr, and KI were measured in n-PrOH-Water mixtures at 25℃. The conductances of these electrolytes increase with the crystalgraphic radii of anions, which are expected from electrotatistical explanation. The concentration effect on the conductance appears to change with the change of composition of the alcohol in solvent mixtures. The association constant K, the ion-size parameter a, and the limitting equivalent conductanc ∧。 were calculated by using the conductance equations. The result have been discussed comparing with the data in water, methanol-water, and ethanolwater. a and K show the tendency to increase with the size of alcohols in solvent mixtures. The ion-size parameter(solvation radii) r_h were also calculated by Walden's rule. This gives considerable lower value than a.
紀要論文
琉球大学理工学部
Science and Engineering Division, University of the Ryukyus
1979-03
eng
departmental bulletin paper
NA
http://hdl.handle.net/20.500.12000/23707
http://hdl.handle.net/20.500.12000/23707
https://u-ryukyu.repo.nii.ac.jp/records/2007012
AN0025080X
琉球大学理工学部紀要. 理学編
Bulletin of Science & Engineering Division, University of Ryukyus. Mathematics & natural sciences
27
57
67
https://u-ryukyu.repo.nii.ac.jp/record/2007012/files/No27p057.pdf