2024-03-29T07:15:30Z
https://u-ryukyu.repo.nii.ac.jp/oai
oai:u-ryukyu.repo.nii.ac.jp:02005240
2022-10-31T02:34:55Z
1642837622505:1642837957109:1642837972945
1642838403551:1642838406414
Kinetic and Electrochemical Studies of N-Benzoylleucomethylene Blue and Hexacyanoferrate (3) Ion in Brij 35-SDS Mixed Micellar Solutions
Kinjo, Akio
Kawahira, Yasushi
Uchihara, Toshio
宇地原, 敏夫
The Kinetic study was carried out for the redox reaction between N-benzoylleucomethylene blue (BLMB) and hexacyanoferrate (3) ion in polyoxyethylenedodecyl ether (Brij35)-sodium dodecyl sulfate (SDS) mixed micellar solutions. No reaction proceeded in the solution containing only Brij 35 micelles.The reaction, however,took place when SDS was added to the Brij 35 micellar solutions, and the rate was increased with increasing the concentration of SDS.The redox potentials of hexacyanoferrate (3) ion and BLMB were measured in the mixed micellar solutions by means of cyclic voltammetry. The oxidation potential of BLMB was suddenly decreased by the addition of SDS to the Brij 35 micellar solutions,while the reduction potential of hexacyanoferrate (3) ion remains almost constant irrespective of the concentration of SDS.
紀要論文
http://purl.org/coar/resource_type/c_6501
琉球大学理学部
1997-09
VoR
http://hdl.handle.net/20.500.12000/15052
0286-9640
AN00250774
琉球大学理学部紀要
Bulletin of the College of Science. University of the Ryukyus
64
68
61
eng
open access