{"created":"2022-01-27T02:46:05.447805+00:00","id":2003023,"links":{},"metadata":{"_buckets":{"deposit":"0f73625a-95cc-4990-a211-034d7a5ea56f"},"_deposit":{"id":"2003023","owners":[1],"pid":{"revision_id":0,"type":"depid","value":"2003023"},"status":"published"},"_oai":{"id":"oai:u-ryukyu.repo.nii.ac.jp:02003023","sets":["1642837622505:1642837905044:1642837913657","1642838403551:1642838407312"]},"author_link":[],"item_1617186331708":{"attribute_name":"Title","attribute_value_mlt":[{"subitem_1551255647225":"\u516d\u54e1\u74b0\u72b6\u30a8\u30ce\u30fc\u30eb\u30ea\u30f3\u5316\u5408\u7269\u306e\u7acb\u4f53\u9078\u629e\u7684\u5408\u6210(\u8fb2\u82b8\u5316\u5b66\u79d1)","subitem_1551255648112":"ja"},{"subitem_1551255647225":"Stereoselective Synthesis of Six-membered Cyclic Enol Phosphorus Compounds (Department of Agricultural Chemistry)","subitem_1551255648112":"en"}]},"item_1617186419668":{"attribute_name":"Creator","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"\u591a\u548c\u7530, \u771f\u5409","creatorNameLang":"ja"}]},{"creatorNames":[{"creatorName":"Tawata, Shinkichi","creatorNameLang":"en"}]}]},"item_1617186476635":{"attribute_name":"Access Rights","attribute_value_mlt":[{"subitem_1522299639480":"open access","subitem_1600958577026":"http://purl.org/coar/access_right/c_abf2"}]},"item_1617186626617":{"attribute_name":"Description","attribute_value_mlt":[{"subitem_description":"2-Phenyl\u53ca\u30732-phenoxy-4-alkylidene-1,3,2-benzodioxaphosphorin 2-oxide\u985e\u3092\u03bf, \u03bf-di(2-alkylketophenyl)phenyl phosphonate\u985e\u53ca\u3073\u03bf-(2-alkylketophenyl)\u03bf, \u03bf-diphenyl phosphate\u985e\u306e\u52a0\u71b1\u306b\u3088\u3063\u3066, \u305d\u308c\u305e\u308c48-70%\u306e\u53ce\u91cf\u3067\u5f97\u305f\u3002\u3053\u306e\u7c21\u5358\u306a\u9589\u74b0\u53cd\u5fdc\u306f\u7acb\u4f53\u9078\u629e\u7684\u306bZ\u4f53\u306e\u307f\u3092\u751f\u3058\u305f\u3002\u3053\u308c\u306f\u304a\u305d\u3089\u304f\u9589\u74b0\u306e\u969b\u306b, \u5869\u57fa\u306e\u4f5c\u7528\u306b\u3088\u3063\u3066\u751f\u3058\u308b\u30a8\u30ce\u30fc\u30eb\u57fa\u304c\u30ea\u30f3\u539f\u5b50\u3092\u653b\u6483\u3059\u308b\u6642\u306b\u306f, \u30d3\u30cb\u30fc\u30eb\u30a2\u30eb\u30ad\u30eb\u57fa\u3068\u30d9\u30f3\u30bc\u30f3\u74b0\u306e5\u4f4d\u306e\u6c34\u7d20\u304c, \u540c\u3058\u5e73\u9762\u69cb\u9020\u4e0a\u306b\u5b58\u5728\u305b\u306d\u3070\u306a\u3089\u306a\u3044\u306e\u3067, \u6700\u3082\u76f8\u4e92\u4f5c\u7528\u304c\u5c11\u306a\u3044Z\u30a8\u30ce\u30fc\u30eb\u3092\u5f62\u6210\u3059\u308b\u304b\u3089\u3067\u3042\u308b\u3068\u601d\u308f\u308c\u305f\u3002","subitem_description_type":"Other"},{"subitem_description":"2-Phenyl-and 2-phenoxy-4-alkylidene-1,3,2-benzodioxaphosphorin 2-oxides are obtained in 48-70% yield on heating O, O-di-(2-alkylketophenyl) phenyl phosphonates and O-(2-alkylketophenyl) O, O-diphenyl phosphates, respectively. This facile cyclization reaction forms only the Z-isomer. The Z-isomer is probably favored because in its formation there is minimal interaction between the vinylic alkyl substituent and aromatic H-5 in the required coplanar conformation for the phenyl and enolate groups to achieve attack at phosphorus.","subitem_description_type":"Other"},{"subitem_description":"\u7d00\u8981\u8ad6\u6587","subitem_description_type":"Other"}]},"item_1617186643794":{"attribute_name":"Publisher","attribute_value_mlt":[{"subitem_1522300295150":"ja","subitem_1522300316516":"\u7409\u7403\u5927\u5b66\u8fb2\u5b66\u90e8"}]},"item_1617186702042":{"attribute_name":"Language","attribute_value_mlt":[{"subitem_1551255818386":"eng"}]},"item_1617186783814":{"attribute_name":"Identifier","attribute_value_mlt":[{"subitem_identifier_type":"HDL","subitem_identifier_uri":"http://hdl.handle.net/20.500.12000/3994"}]},"item_1617186920753":{"attribute_name":"Source Identifier","attribute_value_mlt":[{"subitem_1522646500366":"ISSN","subitem_1522646572813":"0370-4246"},{"subitem_1522646500366":"NCID","subitem_1522646572813":"AN00250548"}]},"item_1617186941041":{"attribute_name":"Source Title","attribute_value_mlt":[{"subitem_1522650068558":"ja","subitem_1522650091861":"\u7409\u7403\u5927\u5b66\u8fb2\u5b66\u90e8\u5b66\u8853\u5831\u544a"},{"subitem_1522650068558":"en","subitem_1522650091861":"The Science Bulletin of the Faculty of Agriculture. University of the Ryukyus"}]},"item_1617187056579":{"attribute_name":"Bibliographic Information","attribute_value_mlt":[{"bibliographicIssueNumber":"30","bibliographicPageEnd":"216","bibliographicPageStart":"211"}]},"item_1617258105262":{"attribute_name":"Resource Type","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_1617265215918":{"attribute_name":"Version Type","attribute_value_mlt":[{"subitem_1522305645492":"VoR","subitem_1600292170262":"http://purl.org/coar/version/c_970fb48d4fbd8a85"}]},"item_1617605131499":{"attribute_name":"File","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_access","filename":"KJ00000162168.pdf","mimetype":"application/pdf","url":{"objectType":"fulltext","url":"https://u-ryukyu.repo.nii.ac.jp/record/2003023/files/KJ00000162168.pdf"},"version_id":"4d4c65b5-5462-462d-8c02-1426b6cc6969"}]},"item_title":"\u516d\u54e1\u74b0\u72b6\u30a8\u30ce\u30fc\u30eb\u30ea\u30f3\u5316\u5408\u7269\u306e\u7acb\u4f53\u9078\u629e\u7684\u5408\u6210(\u8fb2\u82b8\u5316\u5b66\u79d1)","item_type_id":"15","owner":"1","path":["1642837913657","1642838407312"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2008-02-14"},"publish_date":"2008-02-14","publish_status":"0","recid":"2003023","relation_version_is_last":true,"title":["\u516d\u54e1\u74b0\u72b6\u30a8\u30ce\u30fc\u30eb\u30ea\u30f3\u5316\u5408\u7269\u306e\u7acb\u4f53\u9078\u629e\u7684\u5408\u6210(\u8fb2\u82b8\u5316\u5b66\u79d1)"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2022-02-15T05:28:40.884236+00:00"}