{"created":"2022-01-27T02:50:25.838387+00:00","id":2003165,"links":{},"metadata":{"_buckets":{"deposit":"5e7d70ee-d95d-4013-b27a-d7ae66bbda48"},"_deposit":{"id":"2003165","owners":[1],"pid":{"revision_id":0,"type":"depid","value":"2003165"},"status":"published"},"_oai":{"id":"oai:u-ryukyu.repo.nii.ac.jp:02003165","sets":["1642837622505:1642837905044:1642837911830","1642838403551:1642838407312"]},"author_link":[],"item_1617186331708":{"attribute_name":"Title","attribute_value_mlt":[{"subitem_1551255647225":"全トランスーレチナール脂質二重膜における L- システインの光化学反応(農薬生産用農産食料製造)(農芸化学科)","subitem_1551255648112":"ja"},{"subitem_1551255647225":"The photochemical reactions of L-cysteine on all-trans-retinal bilayer lipid membranes (Pesticide-producing Agricultural Food Processing)(Department of Agricultural Chemistry)","subitem_1551255648112":"en"}]},"item_1617186419668":{"attribute_name":"Creator","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"小波本, 直忠","creatorNameLang":"ja"}]},{"creatorNames":[{"creatorName":"大城, 直子","creatorNameLang":"ja"}]},{"creatorNames":[{"creatorName":"Kobamoto, Naotada","creatorNameLang":"en"}]},{"creatorNames":[{"creatorName":"Oshiro, Naoko","creatorNameLang":"en"}]}]},"item_1617186476635":{"attribute_name":"Access Rights","attribute_value_mlt":[{"subitem_1522299639480":"open access","subitem_1600958577026":"http://purl.org/coar/access_right/c_abf2"}]},"item_1617186626617":{"attribute_name":"Description","attribute_value_mlt":[{"subitem_description":"膜で隔てた外室に電子受容体として塩化第二鉄を含む酢酸緩衝液(0.2M)中での全トランス-レチナール脂質二重膜は, 内室へのL-システインの添加により, 光電位の変化を示した。pH値が4.9以下では増強効果が認められ, 4.8において最高となり, 一方, 4.9より高い領域では減少効果が認められた。前者の増強効果は, 光電位発生の主荷電体, ホール, に対するL-システインの酸化還元作用として説明された。後者の減少効果は, 界面における全トランス-レチニルチアゾリジン-4-カルボン酸形成の分光学的影響として説明された。この膜系は, 昆虫の視覚に作用する食料起源の農薬の作用機構の理解と共に, L-システインと同様に作用する視覚阻害剤のスクリーニングにも利用できることが示された。","subitem_description_type":"Other"},{"subitem_description":"The light-induced potentials of an all-trans-retinal bilayer lipid membrane were influenced by the presence of L-cysteine in the aqueous phase, 0.2M sodium acetate buffer, having an electron acceptor, ferric chloride, in the opposite aqueous phase separated by the membrane. In a pH range up to 4.9,an enhancive effect was observed with the maximum at 4.8,whereas in a pH range beyond 4.9 a reductive effect was observed. The former enhancive effect was explained as a redox-related effect of L-cysteine on the major charge carrier, hole, of the photopotentials observed. The latter reductive effect was explained as a spectrophotometric effect of formation of all-trans-retinyl thiazolidine-4-carboxylic acid at the membrane interface. This membrane system was presented to be used for screening the vision inhibitors acting in a way similar to L-cysteine as well as understanding the mechanisms of the action of these potential food-originated pesticides on the insect vision.","subitem_description_type":"Other"},{"subitem_description":"紀要論文","subitem_description_type":"Other"}]},"item_1617186643794":{"attribute_name":"Publisher","attribute_value_mlt":[{"subitem_1522300295150":"ja","subitem_1522300316516":"琉球大学農学部"}]},"item_1617186702042":{"attribute_name":"Language","attribute_value_mlt":[{"subitem_1551255818386":"eng"}]},"item_1617186783814":{"attribute_name":"Identifier","attribute_value_mlt":[{"subitem_identifier_type":"HDL","subitem_identifier_uri":"http://hdl.handle.net/20.500.12000/4155"}]},"item_1617186920753":{"attribute_name":"Source Identifier","attribute_value_mlt":[{"subitem_1522646500366":"ISSN","subitem_1522646572813":"0370-4246"},{"subitem_1522646500366":"NCID","subitem_1522646572813":"AN00250548"}]},"item_1617186941041":{"attribute_name":"Source Title","attribute_value_mlt":[{"subitem_1522650068558":"ja","subitem_1522650091861":"琉球大学農学部学術報告"},{"subitem_1522650068558":"en","subitem_1522650091861":"The Science Bulletin of the Faculty of Agriculture. University of the Ryukyus"}]},"item_1617187056579":{"attribute_name":"Bibliographic Information","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1979-12-11","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"26","bibliographicPageEnd":"158","bibliographicPageStart":"151"}]},"item_1617258105262":{"attribute_name":"Resource Type","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_1617265215918":{"attribute_name":"Version Type","attribute_value_mlt":[{"subitem_1522305645492":"VoR","subitem_1600292170262":"http://purl.org/coar/version/c_970fb48d4fbd8a85"}]},"item_1617605131499":{"attribute_name":"File","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_access","filename":"KJ00000162005.pdf","mimetype":"application/pdf","url":{"objectType":"fulltext","url":"https://u-ryukyu.repo.nii.ac.jp/record/2003165/files/KJ00000162005.pdf"},"version_id":"d57984e2-0cc4-4aec-8069-d12ffdabf061"}]},"item_title":"全トランスーレチナール脂質二重膜における L- システインの光化学反応(農薬生産用農産食料製造)(農芸化学科)","item_type_id":"15","owner":"1","path":["1642837911830","1642838407312"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2008-02-14"},"publish_date":"2008-02-14","publish_status":"0","recid":"2003165","relation_version_is_last":true,"title":["全トランスーレチナール脂質二重膜における L- システインの光化学反応(農薬生産用農産食料製造)(農芸化学科)"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2022-10-31T01:16:45.074846+00:00"}