@article{oai:u-ryukyu.repo.nii.ac.jp:02006677, author = {当馬, 嗣徳 and 石川, 順正 and Toma, Shitoku and Ishikawa, Junsei}, issue = {3}, journal = {琉球大学文理学部紀要 理学篇}, note = {Ultraviolet and visible absorption spectra were taken between 210 and 460 millimicrons in various pH solution (6X10^-5 mole/liter) of Potassium bichromate.Cr_2O^--_7+H_20=2HCrO^-_4 HCrO^-_4=H^++CrO^--_4 Then,in alkaline solution we can consider the next reaction. Cr20^--_7+H_2O = 2H^++2CrO^--_4 Hydrolysis on Cr_20^--_7depends upon pH Concentration and Temperature. When the curves calculated from the visible absorption spectra of potassiumbichromate,having a pH greater than 7.35 Coincided, the solution was considered to be lOO% dissociated.\nFrom theoretical calculation,the solution is 1OO% dissociated at pH greater than 6.99. Curves also coincided at pH blow 5.34, but in this case the solution was not dissociated., 紀要論文}, pages = {1--6}, title = {重クロム酸カリ水溶液に於ける解離度測定について : 熱力学的諸量の分光化学的研究(第1報)} }