@article{oai:u-ryukyu.repo.nii.ac.jp:02006986, author = {Kuniyoshi, Masayuki}, issue = {20}, journal = {琉球大学理工学部紀要. 理学編, Bulletin of Science & Engineering Division, University of Ryukyus. Mathematics & natural sciences}, month = {Sep}, note = {3β-Acetoxy-5α-cholestan-6-one was prepared via several synthetic pathways from cholesterol. It was further converted into brmo-derivatives;5α-bromo-,5α,7α-dibromo-, and 5α,7β-dibromo-6-oxo compounds, in low yields by treatment with bromine in found that the C_5-bromo atom of the 3β-acetoxy-5α-bromocholestan-6-one rearranges to the C_7α position, but not to the C_7β position, by hydrogen bromide in acetic acid to give 7α-bromo-6-oxo compound. Stereochemical studies of these prepared α-bromo-6-oxo compounds were carried out by means of IR, NMR and ORD spectroscopic methods., 紀要論文}, pages = {39--46}, title = {On the Synthesis and the Stareochemical Study of Several α- Bromo - 6 - oxo - steroids Derived from Cholesterol.}, year = {1975} }