{"_buckets": {"deposit": "58f507d8-c468-472a-8a26-963824c9b700"}, "_deposit": {"id": "2003164", "owners": [1], "pid": {"revision_id": 0, "type": "depid", "value": "2003164"}, "status": "published"}, "_oai": {"id": "oai:u-ryukyu.repo.nii.ac.jp:02003164", "sets": ["1642837911830", "1642838407312"]}, "author_link": [], "item_1617186331708": {"attribute_name": "Title", "attribute_value_mlt": [{"subitem_1551255647225": "全トランスーレチナール脂質二重膜における反応の定量的評価法(農薬生産用農産食料製造)(農芸化学科)", "subitem_1551255648112": "ja"}, {"subitem_1551255647225": "A method of quantitative evaluation of reactions on all-trans-retinal bilayer lipid membranes (Pesticide-producing Agricultural Food Processing)(Department of Agricultural Chemistry)", "subitem_1551255648112": "en"}]}, "item_1617186419668": {"attribute_name": "Creator", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "小波本, 直忠", "creatorNameLang": "ja"}]}, {"creatorNames": [{"creatorName": "Kobamoto, Naotada", "creatorNameLang": "en"}]}]}, "item_1617186476635": {"attribute_name": "Access Rights", "attribute_value_mlt": [{"subitem_1522299639480": "open access", "subitem_1600958577026": "http://purl.org/coar/access_right/c_abf2"}]}, "item_1617186626617": {"attribute_name": "Description", "attribute_value_mlt": [{"subitem_description": "脂質二重膜における食料起源農薬の作用の定量的評価法を開拓するため, 分光学的方法によりエタノールー酢酸緩衝液系(0.2M, pH5), および, 光電位測定法により脂質二重膜系で, テトラクロルー1,4-ベンゾキノン(クロラニル)の全トランスーレチナール(組成比1 : 1)との電荷移動錯体(CTC)形成を検討した。このCTCは, 溶液系で, 結合定数が2.6×10^5l/M, CT-帯のエネルギーが2.76eVで, 吸光係数が7450l/Mcmであった。全トランスーレチナールのイオン化ポテンシャルは8.47eVであり, 電位は, クロラニル存在下で, 570%まで増加した。この増強効果は, 結合定数が1.1×10^5l/MのCTCを膜表面において全トランスーレチナールと形成することによるものと考察した。この膜系が, エネルギー変換過程に作用する食料起源農薬のスクリーニング及びそれらの作用機構の解明に利用できることが提案された。", "subitem_description_type": "Other"}, {"subitem_description": "In order to develop the methods of quantitative evaluation of the action of food-originated pesticides on the bilayer lipid membrane, a charge-transfer complex (CTC) of tetrachloro-1,4-benzoquinone (chloranil) and all-trans-retinal (1 : 1 composition) was observed in ethanol acetate buffer (pH 5,0.2M) by a spectrophotometric method and in the membrane system by the method of photoelectric measurement. This CTC had an association constant of 2.6×(10)^5l/M, the energy of CT-band of 2.76eV, and an extinction coefficient of 7450l/Mcm in the solution system. The ionization potential of all-trans-retinal was evaluated as 8.47eV. The light-induced potential developed across the bilayer lipid membrane containing all-trans-retinal was enhanced up to 570% at the presence of chloranil. This enhancement effect of chloranil was disscussed as a result of formation of the CTC with all-trans-retinal at the membrane interface, whose association constant was determined as 1.1×110)^5l/M. It was proposed that the membrane system could be utilized for screening the food-originated pesticides acting on energy-transfer processes and for elucidating their action mechanisms.", "subitem_description_type": "Other"}, {"subitem_description": "紀要論文", "subitem_description_type": "Other"}]}, "item_1617186643794": {"attribute_name": "Publisher", "attribute_value_mlt": [{"subitem_1522300295150": "ja", "subitem_1522300316516": "琉球大学農学部"}]}, "item_1617186702042": {"attribute_name": "Language", "attribute_value_mlt": [{"subitem_1551255818386": "eng"}]}, "item_1617186783814": {"attribute_name": "Identifier", "attribute_value_mlt": [{"subitem_identifier_type": "HDL", "subitem_identifier_uri": "http://hdl.handle.net/20.500.12000/4154"}]}, "item_1617186920753": {"attribute_name": "Source Identifier", "attribute_value_mlt": [{"subitem_1522646500366": "ISSN", "subitem_1522646572813": "0370-4246"}, {"subitem_1522646500366": "NCID", "subitem_1522646572813": "AN00250548"}]}, "item_1617186941041": {"attribute_name": "Source Title", "attribute_value_mlt": [{"subitem_1522650068558": "ja", "subitem_1522650091861": "琉球大学農学部学術報告"}, {"subitem_1522650068558": "en", "subitem_1522650091861": "The Science Bulletin of the Faculty of Agriculture. University of the Ryukyus"}]}, "item_1617187056579": {"attribute_name": "Bibliographic Information", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "1979-12-11", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "26", "bibliographicPageEnd": "150", "bibliographicPageStart": "143"}]}, "item_1617258105262": {"attribute_name": "Resource Type", "attribute_value_mlt": [{"resourcetype": "departmental bulletin paper", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_1617265215918": {"attribute_name": "Version Type", "attribute_value_mlt": [{"subitem_1522305645492": "VoR", "subitem_1600292170262": "http://purl.org/coar/version/c_970fb48d4fbd8a85"}]}, "item_1617605131499": {"attribute_name": "File", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_access", "download_preview_message": "", "file_order": 0, "filename": "KJ00000162004.pdf", "future_date_message": "", "is_thumbnail": false, "mimetype": "", "size": 0, "url": {"objectType": "fulltext", "url": "https://u-ryukyu.repo.nii.ac.jp/record/2003164/files/KJ00000162004.pdf"}, "version_id": "fbe8f657-24f1-4f3f-88e4-835ae8c54bec"}]}, "item_title": "全トランスーレチナール脂質二重膜における反応の定量的評価法(農薬生産用農産食料製造)(農芸化学科)", "item_type_id": "15", "owner": "1", "path": ["1642837911830", "1642838407312"], "permalink_uri": "http://hdl.handle.net/20.500.12000/4154", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2008-02-14"}, "publish_date": "2008-02-14", "publish_status": "0", "recid": "2003164", "relation": {}, "relation_version_is_last": true, "title": ["全トランスーレチナール脂質二重膜における反応の定量的評価法(農薬生産用農産食料製造)(農芸化学科)"], "weko_shared_id": -1}