{"_buckets": {"deposit": "58f507d8-c468-472a-8a26-963824c9b700"}, "_deposit": {"id": "2003164", "owners": [1], "pid": {"revision_id": 0, "type": "depid", "value": "2003164"}, "status": "published"}, "_oai": {"id": "oai:u-ryukyu.repo.nii.ac.jp:02003164", "sets": ["1642837911830", "1642838407312"]}, "author_link": [], "item_1617186331708": {"attribute_name": "Title", "attribute_value_mlt": [{"subitem_1551255647225": "\u5168\u30c8\u30e9\u30f3\u30b9\u30fc\u30ec\u30c1\u30ca\u30fc\u30eb\u8102\u8cea\u4e8c\u91cd\u819c\u306b\u304a\u3051\u308b\u53cd\u5fdc\u306e\u5b9a\u91cf\u7684\u8a55\u4fa1\u6cd5(\u8fb2\u85ac\u751f\u7523\u7528\u8fb2\u7523\u98df\u6599\u88fd\u9020)(\u8fb2\u82b8\u5316\u5b66\u79d1)", "subitem_1551255648112": "ja"}, {"subitem_1551255647225": "A method of quantitative evaluation of reactions on all-trans-retinal bilayer lipid membranes (Pesticide-producing Agricultural Food Processing)(Department of Agricultural Chemistry)", "subitem_1551255648112": "en"}]}, "item_1617186419668": {"attribute_name": "Creator", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "\u5c0f\u6ce2\u672c, \u76f4\u5fe0", "creatorNameLang": "ja"}]}, {"creatorNames": [{"creatorName": "Kobamoto, Naotada", "creatorNameLang": "en"}]}]}, "item_1617186476635": {"attribute_name": "Access Rights", "attribute_value_mlt": [{"subitem_1522299639480": "open access", "subitem_1600958577026": "http://purl.org/coar/access_right/c_abf2"}]}, "item_1617186626617": {"attribute_name": "Description", "attribute_value_mlt": [{"subitem_description": "\u8102\u8cea\u4e8c\u91cd\u819c\u306b\u304a\u3051\u308b\u98df\u6599\u8d77\u6e90\u8fb2\u85ac\u306e\u4f5c\u7528\u306e\u5b9a\u91cf\u7684\u8a55\u4fa1\u6cd5\u3092\u958b\u62d3\u3059\u308b\u305f\u3081, \u5206\u5149\u5b66\u7684\u65b9\u6cd5\u306b\u3088\u308a\u30a8\u30bf\u30ce\u30fc\u30eb\u30fc\u9162\u9178\u7de9\u885d\u6db2\u7cfb(0.2M, pH5), \u304a\u3088\u3073, \u5149\u96fb\u4f4d\u6e2c\u5b9a\u6cd5\u306b\u3088\u308a\u8102\u8cea\u4e8c\u91cd\u819c\u7cfb\u3067, \u30c6\u30c8\u30e9\u30af\u30ed\u30eb\u30fc1,4-\u30d9\u30f3\u30be\u30ad\u30ce\u30f3(\u30af\u30ed\u30e9\u30cb\u30eb)\u306e\u5168\u30c8\u30e9\u30f3\u30b9\u30fc\u30ec\u30c1\u30ca\u30fc\u30eb(\u7d44\u6210\u6bd41 : 1)\u3068\u306e\u96fb\u8377\u79fb\u52d5\u932f\u4f53(CTC)\u5f62\u6210\u3092\u691c\u8a0e\u3057\u305f\u3002\u3053\u306eCTC\u306f, \u6eb6\u6db2\u7cfb\u3067, \u7d50\u5408\u5b9a\u6570\u304c2.6\u00d710^5l/M, CT-\u5e2f\u306e\u30a8\u30cd\u30eb\u30ae\u30fc\u304c2.76eV\u3067, \u5438\u5149\u4fc2\u6570\u304c7450l/Mcm\u3067\u3042\u3063\u305f\u3002\u5168\u30c8\u30e9\u30f3\u30b9\u30fc\u30ec\u30c1\u30ca\u30fc\u30eb\u306e\u30a4\u30aa\u30f3\u5316\u30dd\u30c6\u30f3\u30b7\u30e3\u30eb\u306f8.47eV\u3067\u3042\u308a, \u96fb\u4f4d\u306f, \u30af\u30ed\u30e9\u30cb\u30eb\u5b58\u5728\u4e0b\u3067, 570%\u307e\u3067\u5897\u52a0\u3057\u305f\u3002\u3053\u306e\u5897\u5f37\u52b9\u679c\u306f, \u7d50\u5408\u5b9a\u6570\u304c1.1\u00d710^5l/M\u306eCTC\u3092\u819c\u8868\u9762\u306b\u304a\u3044\u3066\u5168\u30c8\u30e9\u30f3\u30b9\u30fc\u30ec\u30c1\u30ca\u30fc\u30eb\u3068\u5f62\u6210\u3059\u308b\u3053\u3068\u306b\u3088\u308b\u3082\u306e\u3068\u8003\u5bdf\u3057\u305f\u3002\u3053\u306e\u819c\u7cfb\u304c, \u30a8\u30cd\u30eb\u30ae\u30fc\u5909\u63db\u904e\u7a0b\u306b\u4f5c\u7528\u3059\u308b\u98df\u6599\u8d77\u6e90\u8fb2\u85ac\u306e\u30b9\u30af\u30ea\u30fc\u30cb\u30f3\u30b0\u53ca\u3073\u305d\u308c\u3089\u306e\u4f5c\u7528\u6a5f\u69cb\u306e\u89e3\u660e\u306b\u5229\u7528\u3067\u304d\u308b\u3053\u3068\u304c\u63d0\u6848\u3055\u308c\u305f\u3002", "subitem_description_type": "Other"}, {"subitem_description": "In order to develop the methods of quantitative evaluation of the action of food-originated pesticides on the bilayer lipid membrane, a charge-transfer complex (CTC) of tetrachloro-1,4-benzoquinone (chloranil) and all-trans-retinal (1 : 1 composition) was observed in ethanol acetate buffer (pH 5,0.2M) by a spectrophotometric method and in the membrane system by the method of photoelectric measurement. This CTC had an association constant of 2.6\u00d7(10)^5l/M, the energy of CT-band of 2.76eV, and an extinction coefficient of 7450l/Mcm in the solution system. The ionization potential of all-trans-retinal was evaluated as 8.47eV. The light-induced potential developed across the bilayer lipid membrane containing all-trans-retinal was enhanced up to 570% at the presence of chloranil. This enhancement effect of chloranil was disscussed as a result of formation of the CTC with all-trans-retinal at the membrane interface, whose association constant was determined as 1.1\u00d7110)^5l/M. It was proposed that the membrane system could be utilized for screening the food-originated pesticides acting on energy-transfer processes and for elucidating their action mechanisms.", "subitem_description_type": "Other"}, {"subitem_description": "\u7d00\u8981\u8ad6\u6587", "subitem_description_type": "Other"}]}, "item_1617186643794": {"attribute_name": "Publisher", "attribute_value_mlt": [{"subitem_1522300295150": "ja", "subitem_1522300316516": "\u7409\u7403\u5927\u5b66\u8fb2\u5b66\u90e8"}]}, "item_1617186702042": {"attribute_name": "Language", "attribute_value_mlt": [{"subitem_1551255818386": "eng"}]}, "item_1617186783814": {"attribute_name": "Identifier", "attribute_value_mlt": [{"subitem_identifier_type": "HDL", "subitem_identifier_uri": "http://hdl.handle.net/20.500.12000/4154"}]}, "item_1617186920753": {"attribute_name": "Source Identifier", "attribute_value_mlt": [{"subitem_1522646500366": "ISSN", "subitem_1522646572813": "0370-4246"}, {"subitem_1522646500366": "NCID", "subitem_1522646572813": "AN00250548"}]}, "item_1617186941041": {"attribute_name": "Source Title", "attribute_value_mlt": [{"subitem_1522650068558": "ja", "subitem_1522650091861": "\u7409\u7403\u5927\u5b66\u8fb2\u5b66\u90e8\u5b66\u8853\u5831\u544a"}, {"subitem_1522650068558": "en", "subitem_1522650091861": "The Science Bulletin of the Faculty of Agriculture. University of the Ryukyus"}]}, "item_1617187056579": {"attribute_name": "Bibliographic Information", "attribute_value_mlt": [{"bibliographicIssueNumber": "26", "bibliographicPageEnd": "150", "bibliographicPageStart": "143"}]}, "item_1617258105262": {"attribute_name": "Resource Type", "attribute_value_mlt": [{"resourcetype": "departmental bulletin paper", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_1617265215918": {"attribute_name": "Version Type", "attribute_value_mlt": [{"subitem_1522305645492": "VoR", "subitem_1600292170262": "http://purl.org/coar/version/c_970fb48d4fbd8a85"}]}, "item_1617605131499": {"attribute_name": "File", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_access", "download_preview_message": "", "file_order": 0, "filename": "KJ00000162004.pdf", "future_date_message": "", "is_thumbnail": false, "mimetype": "", "size": 0, "url": {"objectType": "fulltext", "url": "https://u-ryukyu.repo.nii.ac.jp/record/2003164/files/KJ00000162004.pdf"}, "version_id": "fbe8f657-24f1-4f3f-88e4-835ae8c54bec"}]}, "item_title": "\u5168\u30c8\u30e9\u30f3\u30b9\u30fc\u30ec\u30c1\u30ca\u30fc\u30eb\u8102\u8cea\u4e8c\u91cd\u819c\u306b\u304a\u3051\u308b\u53cd\u5fdc\u306e\u5b9a\u91cf\u7684\u8a55\u4fa1\u6cd5(\u8fb2\u85ac\u751f\u7523\u7528\u8fb2\u7523\u98df\u6599\u88fd\u9020)(\u8fb2\u82b8\u5316\u5b66\u79d1)", "item_type_id": "15", "owner": "1", "path": ["1642837911830", "1642838407312"], "permalink_uri": "http://hdl.handle.net/20.500.12000/4154", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2008-02-14"}, "publish_date": "2008-02-14", "publish_status": "0", "recid": "2003164", "relation": {}, "relation_version_is_last": true, "title": ["\u5168\u30c8\u30e9\u30f3\u30b9\u30fc\u30ec\u30c1\u30ca\u30fc\u30eb\u8102\u8cea\u4e8c\u91cd\u819c\u306b\u304a\u3051\u308b\u53cd\u5fdc\u306e\u5b9a\u91cf\u7684\u8a55\u4fa1\u6cd5(\u8fb2\u85ac\u751f\u7523\u7528\u8fb2\u7523\u98df\u6599\u88fd\u9020)(\u8fb2\u82b8\u5316\u5b66\u79d1)"], "weko_shared_id": -1}