{"_buckets": {"deposit": "acb4f57a-ed7e-4e90-a8a5-e3bbcdf2dcbb"}, "_deposit": {"id": "2004451", "owners": [1], "pid": {"revision_id": 0, "type": "depid", "value": "2004451"}, "status": "published"}, "_oai": {"id": "oai:u-ryukyu.repo.nii.ac.jp:02004451", "sets": ["1642838403123", "1642838406414"]}, "author_link": [], "item_1617186331708": {"attribute_name": "Title", "attribute_value_mlt": [{"subitem_1551255647225": "\u30d3\u30b9\u30de\u30b9\u30a4\u30aa\u30f3\u3092\u6bcd\u6838\u3068\u3059\u308bp\u3001d\u3001f\u30d6\u30ed\u30c3\u30af : \u5143\u7d20\u3068\u306e\u30d8\u30c6\u30ed\u91d1\u5c5e\u591a\u6838\u932f\u4f53\u306e\u5408\u6210", "subitem_1551255648112": "ja"}, {"subitem_1551255647225": "Synthesis of polynuclear hetero-metal complexes of Bi-p, -d, and -f block elements", "subitem_1551255648112": "en"}]}, "item_1617186419668": {"attribute_name": "Creator", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "\u5b89\u91cc, \u82f1\u6cbb", "creatorNameLang": "ja"}]}, {"creatorNames": [{"creatorName": "Asato, Eiji", "creatorNameLang": "en"}]}]}, "item_1617186476635": {"attribute_name": "Access Rights", "attribute_value_mlt": [{"subitem_1522299639480": "open access", "subitem_1600958577026": "http://purl.org/coar/access_right/c_abf2"}]}, "item_1617186609386": {"attribute_name": "Subject", "attribute_value_mlt": [{"subitem_1522299896455": "ja", "subitem_1522300014469": "Other", "subitem_1523261968819": "\u30d8\u30c6\u30ed\u91d1\u5c5e\u591a\u6838\u932f\u4f53"}, {"subitem_1522299896455": "ja", "subitem_1522300014469": "Other", "subitem_1523261968819": "\u30d3\u30b9\u30de\u30b9"}, {"subitem_1522299896455": "ja", "subitem_1522300014469": "Other", "subitem_1523261968819": "\u8907\u5408\u9178\u5316\u7269"}, {"subitem_1522299896455": "ja", "subitem_1522300014469": "Other", "subitem_1523261968819": "X\u7dda\u7d50\u6676\u69cb\u9020\u89e3\u6790"}, {"subitem_1522299896455": "ja", "subitem_1522300014469": "Other", "subitem_1523261968819": "\u7c89\u672bX\u7dda\u56de\u6298"}, {"subitem_1522299896455": "ja", "subitem_1522300014469": "Other", "subitem_1523261968819": "\u71b1\u5206\u89e3"}, {"subitem_1522299896455": "ja", "subitem_1522300014469": "Other", "subitem_1523261968819": "\u30af\u30e9\u30b9\u30bf\u30fc\u932f\u4f53"}, {"subitem_1522299896455": "en", "subitem_1522300014469": "Other", "subitem_1523261968819": "Polynuclear hetero-metal comnlex"}, {"subitem_1522299896455": "en", "subitem_1522300014469": "Other", "subitem_1523261968819": "Bismuth complex"}, {"subitem_1522299896455": "en", "subitem_1522300014469": "Other", "subitem_1523261968819": "Polymetallic oxide"}, {"subitem_1522299896455": "en", "subitem_1522300014469": "Other", "subitem_1523261968819": "X-ray crystal structure analysis"}, {"subitem_1522299896455": "en", "subitem_1522300014469": "Other", "subitem_1523261968819": "Powder X-ray diffraction"}, {"subitem_1522299896455": "en", "subitem_1522300014469": "Other", "subitem_1523261968819": "Thermal decomposition"}, {"subitem_1522299896455": "en", "subitem_1522300014469": "Other", "subitem_1523261968819": "Cluster comniex"}]}, "item_1617186626617": {"attribute_name": "Description", "attribute_value_mlt": [{"subitem_description": "\u79d1\u7814\u8cbb\u756a\u53f7: 12640543", "subitem_description_type": "Other"}, {"subitem_description": "\u5e73\u621012\uff5e14\u5e74\u5ea6\u79d1\u5b66\u7814\u7a76\u8cbb\u88dc\u52a9\u91d1(\u57fa\u76e4\u7814\u7a76(C)(2))\u7814\u7a76\u6210\u679c\u5831\u544a\u66f8", "subitem_description_type": "Other"}, {"subitem_description": "\uff08\u7814\u7a76\u6982\u8981\uff09\u30d5\u30a8\u30ce\u30ad\u30bd\u67b6\u6a4b\u578b\u4e8c\u6838\u5316\u914d\u4f4d\u5b50\u306b\u7126\u70b9\u3092\u7d5e\u308a\u3001\u300c\u30d3\u30b9\u30de\u30b9\u30a4\u30aa\u30f3\u8a8d\u8b58\u30e6\u30cb\u30c3\u30c8\u300d\u3068\u300c\u7570\u7a2e\u91d1\u5c5e\u8a8d\u8b58\u30e6\u30cb\u30c3\u30c8\u300d\u3092\u7d44\u307f\u8fbc\u3093\u3060\u65b0\u3057\u3044\u975e\u5bfe\u79f0\u578b\u914d\u4f4d\u5b50\u3092\u5408\u6210\u3057\u305f\u3002\u3053\u306e\u914d\u4f4d\u5b50\u306bBi\u3092\u633f\u5165\u3057\u305f\u30e1\u30bf\u30e9\u30b5\u30a4\u30af\u30eb\u578bBi\u5358\u6838\u932f\u4f53\u3092\u51fa\u767a\u539f\u6599\u306b\u7528\u3044\u308b\u4e8b\u3067\u3001\u591a\u69d8\u306aBi-d\u30d6\u30ed\u30c3\u30af\u4e8c\u6838\u7cfb[Bi- V(IV)=O,-Cr(III),-Mn(III),-Fe(III),-Co(III),-Ni(II),-Cu(II)]\u3001Bi-p\u30d6\u30ed\u30c3\u30af\u4e8c\u6838\u7cfb\u932f\u4f53[Bi-Zn(II),-Al(III)]\u304c\u5f97\u3089\u308c\u308b\u4e8b\u3092\u660e\u3089\u304b\u306b\u3057\u305f\u3002\u30d3\u30b9\u30de\u30b9\u932f\u4f53\u306e\u591a\u304f\u306f\u6c34\u3067\u901f\u3084\u304b\u306b\u52a0\u6c34\u5206\u89e3\u3092\u8d77\u3053\u3057\u3001\u4e0d\u6eb6\u6027\u306e\u30d3\u30b9\u30e0\u30c1\u30eb\u5869 (BiO^+)\u3092\u751f\u6210\u3059\u308b\u304c\u3001\u3053\u306e\u4e8c\u6838\u5316\u30ad\u30ec\u30fc\u30c8\u591a\u5ea7\u914d\u4f4d\u5b50\u304b\u3089\u5f97\u3089\u308c\u308bBi(III)-\u7570\u7a2e\u91d1\u5c5e\u7cfb\u932f\u4f53\u306f\u52a0\u6c34\u5206\u89e3\u3092\u8d77\u3053\u3055\u305a\u3001NMR\u6e2c\u5b9a\u304b\u3089\u3082\u6c34\u4e2d\u3067\u5b89\u5b9a\u306b\u9aa8\u683c\u3092\u4fdd\u3064\u4e8b\u304c\u78ba\u8a8d\u3055\u308c\u305f\u3002\\nBi(III)-Cu(II)\u7cfb\u932f\u4f53\u306e\u71b1\u5206\u89e3\u904e\u7a0b\u3092TGA\u3088\u308a\u89e3\u6790\u3057\u305f\u7d50\u679c\u3001300\u2103\u3068\u3044\u3046\u6bd4\u8f03\u7684\u4f4e\u6e29\u3067\u914d\u4f4d\u5b50\u304c\u5b8c\u5168\u306b\u5206\u89e3\u3057\u3001600\u2103\u4ee5\u4e0a\u3067\u306fBi\u306f\u5168\u3066\u8907\u5408\u9178\u5316\u7269\u306b\u306a\u308b\u4e8b\u304cXRD\u6cd5\u306b\u3088\u308a\u78ba\u8a8d\u3055\u308c\u3001\u3053\u306e\u65b9\u6cd5\u304c\u5747\u4e00\u6027\u306e\u9ad8\u3044\u8907\u5408\u9178\u5316\u7269\u3092\u5f97\u308b\u306e\u306b\u6709\u52b9\u306a\u624b\u6cd5\u3067\u3042\u308b\u4e8b\u3092\u63d0\u6848\u3057\u305f\u3002\\n2-\u30d2\u30c9\u30ed\u30ad\u30b7\u30eb\u30a8\u30c1\u30ebN-\u30a4\u30df\u30ce\u30b8\u9162\u9178(H_3heida)\u3092\u7528\u3044\u3066\u3001(NH_4)[Bi_3(heida)_3(OH)]\u30fb 6H_2\u30fbMeOH\u3092\u5408\u6210\u3057\u3001X\u7dda\u69cb\u9020\u89e3\u6790\u306b\u3088\u308a\u03bc-3-OH\u30e6\u30cb\u30c3\u30c8\u3092\u6709\u3059\u308bBi\u4e09\u6838\u30af\u30e9\u30b9\u30bf\u30fc\u3067\u3042\u308b\u3053\u3068\u3092\u660e\u3089\u304b\u306b\u3057\u305f\u3002\u3053\u306e\u932f\u4f53\u306f3\u3064\u306eBi\u30a4\u30aa\u30f3\u304c\u4e0d\u5b8c\u5168\u30ad\u30e5\u30d0\u30f3\u9aa8\u683c\u3092\u5f62\u6210\u3057\u3066\u304a\u308a\u3001\u305d\u306e\u91d1\u5c5e\u6b20\u640d\u90e8\u4f4d\u306bNH_4^+\u30a4\u30aa\u30f3\u304c\u6355\u6349\u3055\u308c\u3066\u3044\u308b\u3002NH_4^+\u30a4\u30aa\u30f3\u306eK^+\u306b\u7f6e\u63db\u3057\u305f\u30ab\u30ea\u30a6\u30e0\u8a98\u5c0e\u4f53\u306e\u5408\u6210\u306b\u6210\u529f\u3057\u3001\u5404\u7a2e\u5206\u5149\u5b66\u7684\u6e2c\u5b9a\u304b\u3089\u3001\u5148\u306eNH_4\u8a98\u5c0e\u4f53\u3068\u540c\u69d8\u306a\u7570\u7a2e\u91d1\u5c5e\u30ad\u30e5\u30d0\u30f3\u9aa8\u683c\u306e\u56db\u6838\u932f\u4f53\u3067\u3042\u308b\u3053\u3068\u3092\u660e\u3089\u304b\u306b\u3057\u3001\u3053\u306e\u65b9\u6cd5\u304cBi_3M\u578b\u7570\u7a2e\u91d1\u5c5e\u30ad\u30e5\u30d0\u30f3\u30af\u30e9\u30b9\u30bf\u30fc\u306e\u5408\u6210\u306b\u6709\u52b9\u3067\u3042\u308b\u4e8b\u3092\u63d0\u6848\u3057\u305f\u3002", "subitem_description_type": "Other"}, {"subitem_description": "In order to establish rational preparative method to create Bi-based hetero-metal dinuclear complexes, a new phenol-based ligand H_6L was prepared. Reaction of H_6L with Bi(N0_3)_3\u30fb5H_2O afforded mononuclear Bi complex [Bi(H_3L)]\u30fbH_2O, where Bi atom is trapped into \"Bi-recognition site\" embedded in the ligand.This complex still contains an empty coordination site for a second metal ion, and indeed reacts with a variety of d-block and p-block elements.Successfully isolated dinuclear complexes are as follows ; Bi-V(IV)=O, -Cr(III), -Mn(III), -Fe(III), -Co(llI), -Ni(II), -Cu(II), -Zn(II), and -AI(III).As potential precursors for polymetallic oxides, thermal decomposition process of these complexes was examined using TGA analysis and XRD measurement.As a representative case, Bi-Cu hetero-nuclear complex loses all of its organic ingredients at around 300\u2103 to become a mixture of Bi_2CuO_4, Bi_2O_3, and CuO.The latter two ingredients further react each other at higher temperatures, and finally causing disappearance of Bi_2O_3 ingredient above 600\u2103.\\nAnother approach to hetero-metal clusters was also examined.A commercially available ligand N-2-hydroxyethyl)iminodiacetic acid(H_3heida)reacts with Bi ion in a mixed solvent of aqueous ammonia and methanol to give trinuclear Bi complex (NH_4)[Bi_3(heida)_3(OH)]\u30fb6H_2O\u30fbMeOH.Its structure is characterized as an incomplete cuban[Bi_3(\u03bc-O_\u003calkoxo\u003ealkoxo)_3(\u03bc_3-OH)], where the three Bi atoms are bridged by the hydroxide ion (\u03bc_3-OH) and adjacent Bi pairs are further bridged by the alkoxo oxygen of heida^\u003c3-\u003e.The metal deficient position of the pre-cubane is occupied by NH^+_4 through hydrogen bonding toward the three bridging alkoxo oxygens.The NH^+_4 can be easily replaced by K^+ to form a mixed cluster [Bi_3K(\u03bc_3-O)_4].This finding suggests that the trinuclear pre-cubane may function as a potential precursor for the mixed clusters of [Bi_3M(\u03bc_3-O)_4] type, where M is d-block and p-block elements, while no such mixed metal clusters have been obtained yet.", "subitem_description_type": "Other"}, {"subitem_description": "\u672a\u516c\u958b\uff1aP.38\u4ee5\u964d\uff08\u5225\u5237\u8ad6\u6587\u306e\u305f\u3081\uff09", "subitem_description_type": "Other"}, {"subitem_description": "\u7814\u7a76\u5831\u544a\u66f8", "subitem_description_type": "Other"}]}, "item_1617186643794": {"attribute_name": "Publisher", "attribute_value_mlt": [{"subitem_1522300295150": "ja", "subitem_1522300316516": "\u5b89\u91cc\u82f1\u6cbb"}]}, "item_1617186702042": {"attribute_name": "Language", "attribute_value_mlt": [{"subitem_1551255818386": "jpn"}]}, "item_1617186783814": {"attribute_name": "Identifier", "attribute_value_mlt": [{"subitem_identifier_type": "HDL", "subitem_identifier_uri": "http://hdl.handle.net/20.500.12000/9267"}]}, "item_1617186920753": {"attribute_name": "Source Identifier", "attribute_value_mlt": [{"subitem_1522646500366": "NCID", "subitem_1522646572813": "BA74249814"}]}, "item_1617258105262": {"attribute_name": "Resource Type", "attribute_value_mlt": [{"resourcetype": "research report", "resourceuri": "http://purl.org/coar/resource_type/c_18ws"}]}, "item_1617265215918": {"attribute_name": "Version Type", "attribute_value_mlt": [{"subitem_1522305645492": "VoR", "subitem_1600292170262": "http://purl.org/coar/version/c_970fb48d4fbd8a85"}]}, "item_1617605131499": {"attribute_name": "File", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_access", "download_preview_message": "", "file_order": 0, "filename": "12640543.pdf", "future_date_message": "", "is_thumbnail": false, "mimetype": "", "size": 0, "url": {"objectType": "fulltext", "url": "https://u-ryukyu.repo.nii.ac.jp/record/2004451/files/12640543.pdf"}, "version_id": "414638d5-ddc8-4aa6-9284-8ca75b9cefa6"}]}, "item_title": "\u30d3\u30b9\u30de\u30b9\u30a4\u30aa\u30f3\u3092\u6bcd\u6838\u3068\u3059\u308bp\u3001d\u3001f\u30d6\u30ed\u30c3\u30af : \u5143\u7d20\u3068\u306e\u30d8\u30c6\u30ed\u91d1\u5c5e\u591a\u6838\u932f\u4f53\u306e\u5408\u6210", "item_type_id": "15", "owner": "1", "path": ["1642838403123", "1642838406414"], "permalink_uri": "http://hdl.handle.net/20.500.12000/9267", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2009-03-17"}, "publish_date": "2009-03-17", "publish_status": "0", "recid": "2004451", "relation": {}, "relation_version_is_last": true, "title": ["\u30d3\u30b9\u30de\u30b9\u30a4\u30aa\u30f3\u3092\u6bcd\u6838\u3068\u3059\u308bp\u3001d\u3001f\u30d6\u30ed\u30c3\u30af : \u5143\u7d20\u3068\u306e\u30d8\u30c6\u30ed\u91d1\u5c5e\u591a\u6838\u932f\u4f53\u306e\u5408\u6210"], "weko_shared_id": -1}