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Local Stark Mixing in the Phosphorescent Processes of p-Benzoquinone
http://hdl.handle.net/20.500.12000/14211
http://hdl.handle.net/20.500.12000/1421158d082ba-7d0b-4742-8f48-8855c7a00ac0
名前 / ファイル | ライセンス | アクション |
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No55p019.pdf
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Item type | デフォルトアイテムタイプ(フル)(1) | |||||||||
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公開日 | 2009-12-22 | |||||||||
タイトル | ||||||||||
タイトル | Local Stark Mixing in the Phosphorescent Processes of p-Benzoquinone | |||||||||
言語 | en | |||||||||
作成者 |
Miyagi, Yusei
× Miyagi, Yusei
× 宮城, 雄清
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アクセス権 | ||||||||||
アクセス権 | open access | |||||||||
アクセス権URI | http://purl.org/coar/access_right/c_abf2 | |||||||||
内容記述 | ||||||||||
内容記述タイプ | Other | |||||||||
内容記述 | The phosphorescence spectra of p-benzoquinone are very sensitive to environments and electric fields since the molecule have small energy gaps between the first and second excited triplet states. The variable vibronic pattern from solvent to solvent is a manifestationof perturbation between the two triplet n π* states. The calculation of the local field strength of dipolar environments indicates that the effective electric fields coming from the environmental dipolar pertrubations in polar solvents or binary-mixed nonpolar solvents are~10^6 V/cm in order of magnitude in external bulk scales. It is also demonstrated that these rather intense fields lead the drastic increments of the phosphorescence origin band due to the local Stark mixing between ^3B_<1g>(n,π*) and ^3A_u(n_1π*). Coupling matrix element obtained due to the solvent Stark fields is 212 cm^<-1>. | |||||||||
内容記述 | ||||||||||
内容記述タイプ | Other | |||||||||
内容記述 | 紀要論文 | |||||||||
出版者 | ||||||||||
言語 | ja | |||||||||
出版者 | 琉球大学理学部 | |||||||||
言語 | ||||||||||
言語 | eng | |||||||||
資源タイプ | ||||||||||
資源タイプ | departmental bulletin paper | |||||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||||||
出版タイプ | ||||||||||
出版タイプ | VoR | |||||||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||||||
識別子 | ||||||||||
識別子 | http://hdl.handle.net/20.500.12000/14211 | |||||||||
識別子タイプ | HDL | |||||||||
収録物識別子 | ||||||||||
収録物識別子タイプ | ISSN | |||||||||
収録物識別子 | 0286-9640 | |||||||||
収録物識別子 | ||||||||||
収録物識別子タイプ | NCID | |||||||||
収録物識別子 | AN00250774 | |||||||||
収録物名 | ||||||||||
言語 | ja | |||||||||
収録物名 | 琉球大学理学部紀要 | |||||||||
収録物名 | ||||||||||
言語 | en | |||||||||
収録物名 | Bulletin of the College of Science. University of the Ryukyus | |||||||||
書誌情報 |
号 55, p. 19-25, 発行日 1993-03 |