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  1. 紀要論文
  2. 琉球大学理学部紀要
  3. 55号
  1. 部局別インデックス
  2. 理学部

Local Stark Mixing in the Phosphorescent Processes of p-Benzoquinone

http://hdl.handle.net/20.500.12000/14211
http://hdl.handle.net/20.500.12000/14211
58d082ba-7d0b-4742-8f48-8855c7a00ac0
名前 / ファイル ライセンス アクション
No55p019.pdf No55p019.pdf
Item type デフォルトアイテムタイプ(フル)(1)
公開日 2009-12-22
タイトル
タイトル Local Stark Mixing in the Phosphorescent Processes of p-Benzoquinone
言語 en
作成者 Miyagi, Yusei

× Miyagi, Yusei

en Miyagi, Yusei

宮城, 雄清

× 宮城, 雄清

ja 宮城, 雄清

アクセス権
アクセス権 open access
アクセス権URI http://purl.org/coar/access_right/c_abf2
内容記述
内容記述タイプ Other
内容記述 The phosphorescence spectra of p-benzoquinone are very sensitive to environments and electric fields since the molecule have small energy gaps between the first and second excited triplet states. The variable vibronic pattern from solvent to solvent is a manifestationof perturbation between the two triplet n π* states. The calculation of the local field strength of dipolar environments indicates that the effective electric fields coming from the environmental dipolar pertrubations in polar solvents or binary-mixed nonpolar solvents are~10^6 V/cm in order of magnitude in external bulk scales. It is also demonstrated that these rather intense fields lead the drastic increments of the phosphorescence origin band due to the local Stark mixing between ^3B_<1g>(n,π*) and ^3A_u(n_1π*). Coupling matrix element obtained due to the solvent Stark fields is 212 cm^<-1>.
内容記述タイプ Other
内容記述 紀要論文
出版者
言語 ja
出版者 琉球大学理学部
言語
言語 eng
資源タイプ
資源タイプ departmental bulletin paper
資源タイプ識別子 http://purl.org/coar/resource_type/c_6501
出版タイプ
出版タイプ VoR
出版タイプResource http://purl.org/coar/version/c_970fb48d4fbd8a85
識別子
識別子 http://hdl.handle.net/20.500.12000/14211
識別子タイプ HDL
収録物識別子
収録物識別子タイプ ISSN
収録物識別子 0286-9640
収録物識別子タイプ NCID
収録物識別子 AN00250774
収録物名
言語 ja
収録物名 琉球大学理学部紀要
書誌情報
号 55, p. 19-25, 発行日 1993-03
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