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  1. 紀要論文
  2. 琉球大学理学部紀要
  3. 61号
  1. 部局別インデックス
  2. 理学部

Kinetic Studies of the Redox Reaction between N-Benzoylleucomethylene Blue and Hexacyanoferrate (3) Ions in SDS-Hydrocarbon Mixed Micellar Solutions

http://hdl.handle.net/20.500.12000/15053
http://hdl.handle.net/20.500.12000/15053
e25e5687-f887-4b52-b6d6-72743d411fb2
名前 / ファイル ライセンス アクション
No61p001.pdf No61p001.pdf
Item type デフォルトアイテムタイプ(フル)(1)
公開日 2010-01-25
タイトル
タイトル Kinetic Studies of the Redox Reaction between N-Benzoylleucomethylene Blue and Hexacyanoferrate (3) Ions in SDS-Hydrocarbon Mixed Micellar Solutions
言語 en
作成者 Uejoh, Kazuya

× Uejoh, Kazuya

en Uejoh, Kazuya

Uchihara, Toshio

× Uchihara, Toshio

en Uchihara, Toshio

Kinjo, Akio

× Kinjo, Akio

en Kinjo, Akio

宇地原, 敏夫

× 宇地原, 敏夫

ja 宇地原, 敏夫

アクセス権
アクセス権 open access
アクセス権URI http://purl.org/coar/access_right/c_abf2
内容記述
内容記述タイプ Other
内容記述 The second-order rate constant was measured for the reaction between N-benzoylleucomethylene blue (BLMB) and hexacyanoferrate (3) ions by using the stopped flow spectrophotometric technique in sodium dodecylsulfate (SDS)-hexane, SDS - heptane and SDS - octane mixed micellar solutions. The rate constant increased with increasing the molecular fraction of SDS in the mixed micelles for all the hydrocarbons used, despite electrostatic repulsion between the negative surface charge of the micelles and hexacyanoferrate (3) anions. The results seem to support the conclusion that electrostatic stabilization of methylene blue (MB) cations (reaction product) by the negative surface charge of the micelles is the driving force for the reaction.
内容記述タイプ Other
内容記述 紀要論文
出版者
言語 ja
出版者 琉球大学理学部
言語
言語 eng
資源タイプ
資源タイプ departmental bulletin paper
資源タイプ識別子 http://purl.org/coar/resource_type/c_6501
出版タイプ
出版タイプ VoR
出版タイプResource http://purl.org/coar/version/c_970fb48d4fbd8a85
識別子
識別子 http://hdl.handle.net/20.500.12000/15053
識別子タイプ HDL
収録物識別子
収録物識別子タイプ ISSN
収録物識別子 0286-9640
収録物識別子タイプ NCID
収録物識別子 AN00250774
収録物名
言語 ja
収録物名 琉球大学理学部紀要
書誌情報
号 61, p. 1-8
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