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  1. 紀要論文
  2. 琉球大学理工学部紀要 理学編
  3. 18号
  1. 部局別インデックス
  2. 理学部

Kinetie Studies of Photochemical Addition of Iodine to Cyclohexene

http://hdl.handle.net/20.500.12000/23508
http://hdl.handle.net/20.500.12000/23508
9fd61c6b-92be-4a57-927d-087d714e2eac
名前 / ファイル ライセンス アクション
No18p067.pdf No18p067.pdf
Item type デフォルトアイテムタイプ(フル)(1)
公開日 2012-02-28
タイトル
タイトル Kinetie Studies of Photochemical Addition of Iodine to Cyclohexene
言語 en
作成者 Kinjo, Akio

× Kinjo, Akio

en Kinjo, Akio

Uchihara, Toshio

× Uchihara, Toshio

en Uchihara, Toshio

Toma, Shitoku

× Toma, Shitoku

en Toma, Shitoku

Kinjo, Yoshiaki

× Kinjo, Yoshiaki

en Kinjo, Yoshiaki

金城, 昭夫

× 金城, 昭夫

ja 金城, 昭夫

宇地原, 敏夫

× 宇地原, 敏夫

ja 宇地原, 敏夫

当間, 嗣徳

× 当間, 嗣徳

ja 当間, 嗣徳

金城, 嘉昭

× 金城, 嘉昭

ja 金城, 嘉昭

アクセス権
アクセス権 open access
アクセス権URI http://purl.org/coar/access_right/c_abf2
内容記述
内容記述タイプ Other
内容記述 Several mechanisms have been proposed for the addition of iodine to double bond. We have studied kinetics of the addition of iodine to cyclohexene under the irradiation of the sample solution at the iodine absorption band in visible region and at the charge transfer band in ultraviolet region of the electron donor acceptor complex between iodine and cyc1ohexene. The apparent order of the reaction was 3/2 and 0.64 with respect to iodine and cyc1ohexene, respectively, when the sample solution was illuminated with visible light. We observed an evidence to suggest that the complex participates in the reaction from the study of temperature effect on the kinetics. However, kinetic data could not be fully explained by the complex participation mechanism alone. The experimental results seem to be explained by co-occurance of radical chain mechanism and complex participation mechanism in parallel. In case of the illumination of the solution with 315 nm light, the apparent order of the reaction was 2 and 0.64 with respect to iodine and cyclohexene, respectively. The electron donor acceptor complex may produce radicals upon the charge transfer absorption, and the subsequent eaction seems to proceed in the same way as illuminated with visible light because the apparent reaction order with respect to cyclohexene is same.
内容記述タイプ Other
内容記述 紀要論文
出版者
言語 ja
出版者 琉球大学理工学部
言語
言語 eng
資源タイプ
資源タイプ departmental bulletin paper
資源タイプ識別子 http://purl.org/coar/resource_type/c_6501
出版タイプ
出版タイプ NA
出版タイプResource http://purl.org/coar/version/c_be7fb7dd8ff6fe43
識別子
識別子 http://hdl.handle.net/20.500.12000/23508
識別子タイプ HDL
収録物識別子
収録物識別子タイプ NCID
収録物識別子 AN0025080X
収録物名
言語 ja
収録物名 琉球大学理工学部紀要. 理学編
書誌情報
号 18, p. 67-80
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