{"_buckets": {"deposit": "0c2cf2de-db6d-41fd-9f4e-7dbfb0d52142"}, "_deposit": {"id": "2009691", "owners": [1], "pid": {"revision_id": 0, "type": "depid", "value": "2009691"}, "status": "published"}, "_oai": {"id": "oai:u-ryukyu.repo.nii.ac.jp:02009691", "sets": ["1642837930013", "1642838407312"]}, "author_link": [], "item_1617186331708": {"attribute_name": "Title", "attribute_value_mlt": [{"subitem_1551255647225": "Assignment of the absolute configuration of 3,6-anhydrogalactose derivatives via diastereomeric glycosylation of threose derivatives obtained by periodate Oxidation.", "subitem_1551255648112": "en"}, {"subitem_1551255647225": "\u904e\u30e8\u30a6\u7d20\u9178\u9178\u5316\u306b\u3088\u308b\u30c8\u30ec\u30aa\u30fc\u30b9\u8a98\u5c0e\u4f53\u306e\u30b0\u30ea\u30b3\u30b7\u30c9\u30b8\u30a2\u30b9\u30c6\u30ec\u30aa\u30de\u30fc\u3092\u7d4c\u7531\u3057\u305f3,6-\u30a2\u30f3\u30d2\u30c9\u30ed\u30ac\u30e9\u30af\u30c8\u30fc\u30b9\u306e\u7d76\u5bfe\u914d\u7f6e\u306e\u5e30\u5c5e", "subitem_1551255648112": "ja"}]}, "item_1617186419668": {"attribute_name": "Creator", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Takano, Ryo", "creatorNameLang": "en"}]}, {"creatorNames": [{"creatorName": "Tohma, Yurina", "creatorNameLang": "en"}]}, {"creatorNames": [{"creatorName": "\u9ad8\u91ce, \u826f", "creatorNameLang": "ja"}]}, {"creatorNames": [{"creatorName": "\u7576\u9593, \u512a\u91cc\u83dc", "creatorNameLang": "ja"}]}]}, "item_1617186476635": {"attribute_name": "Access Rights", "attribute_value_mlt": [{"subitem_1522299639480": "open access", "subitem_1600958577026": "http://purl.org/coar/access_right/c_abf2"}]}, "item_1617186609386": {"attribute_name": "Subject", "attribute_value_mlt": [{"subitem_1522299896455": "en", "subitem_1522300014469": "Other", "subitem_1523261968819": "absolute configuration"}, {"subitem_1522299896455": "en", "subitem_1522300014469": "Other", "subitem_1523261968819": "3,6-anhydrogalactose"}, {"subitem_1522299896455": "en", "subitem_1522300014469": "Other", "subitem_1523261968819": "agar"}, {"subitem_1522299896455": "en", "subitem_1522300014469": "Other", "subitem_1523261968819": "carrageenan"}, {"subitem_1522299896455": "en", "subitem_1522300014469": "Other", "subitem_1523261968819": "red seaweed"}, {"subitem_1522299896455": "ja", "subitem_1522300014469": "Other", "subitem_1523261968819": "\u7d76\u5bfe\u914d\u7f6e"}, {"subitem_1522299896455": "ja", "subitem_1522300014469": "Other", "subitem_1523261968819": "3,6-\u30a2\u30f3\u30d2\u30c9\u30ed\u30ac\u30e9\u30af\u30c8\u30fc\u30b9"}, {"subitem_1522299896455": "ja", "subitem_1522300014469": "Other", "subitem_1523261968819": "\u5bd2\u5929"}, {"subitem_1522299896455": "ja", "subitem_1522300014469": "Other", "subitem_1523261968819": "\u30ab\u30e9\u30ae\u30fc\u30ca\u30f3"}, {"subitem_1522299896455": "ja", "subitem_1522300014469": "Other", "subitem_1523261968819": "\u7d05\u85fb"}]}, "item_1617186626617": {"attribute_name": "Description", "attribute_value_mlt": [{"subitem_description": "In order to assign the absolute configuration of 3,6-anhydrogalactose and its 2-Omethylether, their dimethylacetals were subjected to periodate oxidation to yield 3-O-(2-hydroxy-methyl) threose dimethylacetal derivatives, which were further derivatized to the diastereomeric glycosides with (R)- or (S)-2-octanol. Their TMS derivatives were completely resolved by gas-liquid chromatography. Complication in the chromatogram due to contaminants or by-products, when this procedure was applied to total methanolysate of the red algal galactans, was overcome by monitoring the fragment ion of m/z = 116 in the mass spectra using selected ion monitor (SIM)chromatogram using GC-MS.", "subitem_description_type": "Other"}, {"subitem_description": "\u7d05\u85fb\u306e\u591a\u7cd6\u306e\u4e3b\u8981\u6210\u5206\u3067\u3042\u308b3,6-\u30a2\u30f3\u30d2\u30c9\u30ed\u30ac\u30e9\u30af\u30c8\u30fc\u30b9\u306e\u7d76\u5bfe\u914d\u7f6e\u3092\u5e30\u5c5e\u3059\u308b\u305f\u3081\u30013,6-\u30a2\u30f3\u30d2\u30c9\u30ed\u30ac\u30e9\u30af\u30c8\u30fc\u30b9\u30b8\u30e1\u30c1\u30eb\u30a2\u30bb\u30bf\u30fc\u30eb\u3092\u904e\u30e8\u30a6\u7d20\u9178\u9178\u5316\u3057\u30663-O-(2-\u30d2\u30c9\u30ed\u30ad\u30b7\u30e1\u30c1\u30eb)\u30c8\u30ec\u30aa\u30fc\u30b9\u30b8\u30e1\u30c1\u30eb\u30a2\u30bb\u30bf\u30fc\u30eb\u306b\u5909\u63db\u3057\u3001\u3055\u3089\u306b\u3053\u306e\u3082\u306e\u3092(R)-\u307e\u305f\u306f(S)-2-\u30aa\u30af\u30bf\u30ce\u30fc\u30eb\u3068\u306e\u30b8\u30a2\u30b9\u30c6\u30ec\u30aa\u30de\u30fc\u306e\u30b0\u30ea\u30b3\u30b7\u30c9\u306b\u5c0e\u3044\u305f\u3002\u3053\u308c\u3089\u3092TMS \u8a98\u5c0e\u4f53\u3068\u3057\u3066GLC \u5206\u6790\u3057\u305f\u3068\u3053\u308d\u3001\u4e21\u30b8\u30a2\u30b9\u30c6\u30ec\u30aa\u30de\u30fc\u306f\u5b8c\u5168\u306b\u5206\u96e2\u3055\u308c\u305f\u3002\u307e\u305f\u30013,6-\u30a2\u30f3\u30d2\u30c9\u30ed-2-O-\u30e1\u30c1\u30eb\u30ac\u30e9\u30af\u30c8\u30fc\u30b9\u3082\u540c\u69d8\u306b\u5206\u96e2\u3059\u308b\u3053\u3068\u304c\u3067\u304d\u305f\u3002\u3053\u306e\u65b9\u6cd5\u3092\u7d05\u85fb\u591a\u7cd6\u306e\u5b8c\u5168\u30e1\u30bf\u30ce\u30ea\u30b7\u30b9\u5316\u7269\u306b\u9069\u7528\u3059\u308b\u3068\u3001\u30af\u30ed\u30de\u30c8\u30b0\u30e9\u30e0\u306f\u593e\u96d1\u7269\u307e\u305f\u306f\u526f\u751f\u6210\u7269\u306b\u3088\u308a\u8907\u96d1\u5316\u3059\u308b\u304c\u3001GC-MS \u3092\u7528\u3044\u3001m/z = 116 \u306e\u30d5\u30e9\u30b0\u30e1\u30f3\u30c8\u30a4\u30aa\u30f3\u3092\u7528\u3044\u305fSIM \u30af\u30ed\u30de\u30c8\u30b0\u30e9\u30d5\u30a3\u30fc\u3092\u9069\u7528\u3059\u308b\u3053\u3068\u306b\u3088\u308a\u89e3\u6c7a\u3055\u308c\u305f\u3002", "subitem_description_type": "Other"}, {"subitem_description": "\u7d00\u8981\u8ad6\u6587", "subitem_description_type": "Other"}]}, "item_1617186643794": {"attribute_name": "Publisher", "attribute_value_mlt": [{"subitem_1522300295150": "ja", "subitem_1522300316516": "\u7409\u7403\u5927\u5b66\u8fb2\u5b66\u90e8"}]}, "item_1617186702042": {"attribute_name": "Language", "attribute_value_mlt": [{"subitem_1551255818386": "eng"}]}, "item_1617186783814": {"attribute_name": "Identifier", "attribute_value_mlt": [{"subitem_identifier_type": "HDL", "subitem_identifier_uri": "http://hdl.handle.net/20.500.12000/40910"}]}, "item_1617186920753": {"attribute_name": "Source Identifier", "attribute_value_mlt": [{"subitem_1522646500366": "ISSN", "subitem_1522646572813": "0370-4246"}, {"subitem_1522646500366": "NCID", "subitem_1522646572813": "AN00250548"}]}, "item_1617186941041": {"attribute_name": "Source Title", "attribute_value_mlt": [{"subitem_1522650068558": "ja", "subitem_1522650091861": "\u7409\u7403\u5927\u5b66\u8fb2\u5b66\u90e8\u5b66\u8853\u5831\u544a"}, {"subitem_1522650068558": "en", "subitem_1522650091861": "THE SCIENCE BULLETIN OF THE FACULTY OF AGRICULTURE UNIVERSITY OF THE RYUKYUS"}]}, "item_1617187056579": {"attribute_name": "Bibliographic Information", "attribute_value_mlt": [{"bibliographicIssueNumber": "64", "bibliographicPageEnd": "39", "bibliographicPageStart": "33"}]}, "item_1617258105262": {"attribute_name": "Resource Type", "attribute_value_mlt": [{"resourcetype": "departmental bulletin paper", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_1617265215918": {"attribute_name": "Version Type", "attribute_value_mlt": [{"subitem_1522305645492": "VoR", "subitem_1600292170262": "http://purl.org/coar/version/c_970fb48d4fbd8a85"}]}, "item_1617605131499": {"attribute_name": "File", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_access", "download_preview_message": "", "file_order": 0, "filename": "No64p033.pdf", "future_date_message": "", "is_thumbnail": false, "mimetype": "", "size": 0, "url": {"objectType": "fulltext", "url": "https://u-ryukyu.repo.nii.ac.jp/record/2009691/files/No64p033.pdf"}, "version_id": "0b285c3d-1847-4459-b212-4f9a53903cef"}]}, "item_title": "Assignment of the absolute configuration of 3,6-anhydrogalactose derivatives via diastereomeric glycosylation of threose derivatives obtained by periodate Oxidation.", "item_type_id": "15", "owner": "1", "path": ["1642837930013", "1642838407312"], "permalink_uri": "http://hdl.handle.net/20.500.12000/40910", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2018-04-26"}, "publish_date": "2018-04-26", "publish_status": "0", "recid": "2009691", "relation": {}, "relation_version_is_last": true, "title": ["Assignment of the absolute configuration of 3,6-anhydrogalactose derivatives via diastereomeric glycosylation of threose derivatives obtained by periodate Oxidation."], "weko_shared_id": -1}
過ヨウ素酸酸化によるトレオース誘導体のグリコシドジアステレオマーを経由した3,6-アンヒドロガラクトースの絶対配置の帰属
http://hdl.handle.net/20.500.12000/40910
http://hdl.handle.net/20.500.12000/40910